- First performance was in a Houston beer commercial.
- (2004) TV commercial and print ads for Stetson cologne.
- (2000) "Don't Mess with Texas" anti-littering television ads.
- Exxon Tiger Spirit Service.
- (2008) TV commercial for Dolce and Gabbana.
- (January 2008) Became the new national spokesperson for the Beef Industry Council, continuing their radio and television campaign, "Beef. It's What's For Dinner," and replacing long time previous spokesman Sam Elliott (voiceover).
- (2003) Appeared in the remix version of Keith Urban's music video "Somebody Like You," which was re-produced as the theme song for McConaughey's movie, How to Lose a Guy in 10 Days (2003).
- (2010) Print ads for the Entertainment Industry Foundation's "Welcome Back Veterans" service campaign.
- (November 2013) TV commercial, with Scarlett Johansson, for Dolce & Gabbana The One perfume/colognes.
- (2006) Radio commercial for the US Peace Corps.
- (2006) TV commercial for the US Peace Corps (voiceover).
- (September 2014) TV commercial, "I've Been Driving Lincolns Since Before They Paid Me," for the new 2015 Lincoln MKC luxury utility.
- (September 2014) TV commercial, "Sometimes You Have to Go Backwards to Go Forwards," for the new 2015 Lincoln MKC luxury sport utility.
- (2014) Print advertisement (w/ Scarlett Johansson) for DOLCE & GABBANA's "The One" fragrances for men and women - Model
- (2016) TV commercial for Wild Turkey bourbon whiskey
- (December 27, 2019) Commercial: "The All-New 2020 Lincoln Aviator \ Warm Escape \ Lincoln"
- (2021) Release of his memoir "Greenlights".
- (2023) Release of his children's book, "Just Because".
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