In a 1903 flashback, Lily Salvatore calls Enzo by his real first name Lorenzo.
Given that it has been established that Whitmore College and Scull Bar, while in a town close to Mystic Falls, are not actually in Mystic Falls, it is not explained why Matt and Tyler would be doing their training run for the Mystic Falls police in that town rather than Mystic Falls and thus end up at Scull Bar where Matt had not previously been seen to hang out.
The title of this episode, 'I Could Never Love Like That,' comes from a popular 1903 song composed by Elmer Bowman (lyrics) and Al Johns (music). It was sung by vocalist Billy Murray.